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Describe using chemical equations the chain reaction process whereby chlorine free radicals break down ozone in the stratosphere. - Leaving Cert Chemistry - Question A - 2005

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Describe using chemical equations the chain reaction process whereby chlorine free radicals break down ozone in the stratosphere.

Worked Solution & Example Answer:Describe using chemical equations the chain reaction process whereby chlorine free radicals break down ozone in the stratosphere. - Leaving Cert Chemistry - Question A - 2005

Step 1

Step 1: Initiation Reaction

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Answer

The process begins with the initiation of chlorine-free radicals in the stratosphere. This can be represented by the equation:

Cl+O3ClO+O2Cl \cdot + O_3 \rightarrow ClO \cdot + O_2

In this reaction, a chlorine radical reacts with ozone (O₃) to form a chlorine monoxide radical (ClO) and molecular oxygen (O₂).

Step 2

Step 2: Propagation Reaction

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The ClO radical can then undergo further reactions to propagate the chain reaction. This is represented by:

ClO+OCl+O2ClO \cdot + O \rightarrow Cl \cdot + O_2

Here, the chlorine monoxide radical reacts with a free oxygen atom, releasing the original chlorine radical (Cl) and producing more molecular oxygen (O₂).

Step 3

Step 3: Termination Reaction

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Finally, the chain reaction can terminate with the following reaction:

ClO+Cl2ClClO \cdot + Cl \cdot \rightarrow 2Cl

This indicates that two chlorine radicals react to form a stable compound, thereby terminating the chain reaction. However, the cycle can continue as long as chlorine radicals are present.

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