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Study the reaction scheme and answer the questions below - Leaving Cert Chemistry - Question 8 - 2020

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Study the reaction scheme and answer the questions below. $$C_2H_4$$ (i) Identify in the scheme (i) a substitution reaction, (ii) an addition reaction, (iii) an el... show full transcript

Worked Solution & Example Answer:Study the reaction scheme and answer the questions below - Leaving Cert Chemistry - Question 8 - 2020

Step 1

Identify in the scheme (i) a substitution reaction, (ii) an addition reaction, (iii) an elimination reaction.

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Answer

  1. Substitution Reaction: The transformation from C2H5ClC_2H_5Cl to C2H4C_2H_4 involving the replacement of chlorine by hydrogen in the presence of a suitable reagent.

  2. Addition Reaction: The conversion from C2H4C_2H_4 to C2H6C_2H_6, where additional hydrogen is added to the double bond of ethene.

  3. Elimination Reaction: The conversion of C2H4C_2H_4 to C2H2C_2H_2, which involves the removal of a small molecule, resulting in the formation of a double bond.

Step 2

What reagent and catalyst can be used in conversion 1?

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Answer

In conversion 1, the reagent used is hydrogen (H2H_2) and the catalyst can be nickel (NiNi), palladium (PdPd), or platinum (PtPt).

Step 3

Copy the structure of ethanol and identify clearly the bonds formed during conversion 1.

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Answer

The structure of ethanol is as follows:

    H   H
    |   |
H - C - C - O - H
    |   |
    H   H

In conversion 1, the bonds formed include:

  • The C-H bonds are created when hydrogen is added to the carbon atoms.
  • The C-O bond is present in the ethanol structure.

Step 4

Identify an organic substance in the scheme that is highly soluble in water. Justify your answer.

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Answer

The organic substance that is highly soluble in water is ethanol (C2H5OHC_2H_5OH). This is due to the presence of the hydroxyl (−OH-OH) group which can form hydrogen bonds with water molecules, enhancing its solubility.

Step 5

Identify compound X.

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Answer

Compound X is identified as chloroethene (monochloroethene or vinyl chloride, C2H3ClC_2H_3Cl).

Step 6

How does the geometry around the carbon atoms change during conversion 7?

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Answer

During conversion 7, the geometry changes from trigonal planar around the carbon atom in chloroethene to tetrahedral when it converts to ethane, following the saturation of the double bond.

Step 7

Draw the structure of two repeating units of the polymer PVC.

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Answer

The repeating unit of polyvinyl chloride (PVC) can be represented as:

   Cl   H   H   H
    |    |    |  
--C--C--C--C--
   |   |  |   |
   H   H   Cl   Cl

where the structure consists of alternating carbon atoms, with chlorine atoms attached, representing the polymer's repeating unit.

Step 8

Describe a mechanism, that involves ions, for conversion 6.

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Answer

In conversion 6, the mechanism involves the following steps:

  1. Initiation: Chlorine (Cl2Cl_2) undergoes heterolytic fission to form two chloride ions (Cl−Cl^-).
  2. Formation of Carbocation: The carbon atom adjacent to the chlorine will form a carbocation (C+C^+) as the double bond breaks.
  3. Nucleophilic attack: The Cl−Cl^- ion attacks the carbocation, resulting in the formation of the final product.
    This mechanism illustrates the importance of ionic species in facilitating organic reactions.

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