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Define rate of a chemical reaction - Leaving Cert Chemistry - Question 7 - 2003

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Define rate of a chemical reaction. Calcium carbonate (marble chips) reacts with hydrochloric acid according to the following equation. CaCO₃ + 2HCl → CaCl₂ + CO₂ ... show full transcript

Worked Solution & Example Answer:Define rate of a chemical reaction - Leaving Cert Chemistry - Question 7 - 2003

Step 1

Define rate of a chemical reaction.

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Answer

The rate of a chemical reaction can be defined as the change in concentration of a reactant or product per unit time. Mathematically, this can be represented as:

extRate=Δ[A]Δt ext{Rate} = \frac{\Delta [A]}{\Delta t}

where ([A]) is the concentration and (t) is time.

Step 2

i) particle size

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Answer

To demonstrate the effect of particle size on the rate of reaction, one can use marble chips of different sizes. The experiment involves:

  1. Preparation: Measure equal masses of marble chips of varying sizes (large, medium, small).
  2. Reactants: Use equal concentrations of hydrochloric acid (HCl) and add to each set of marble chips in separate beakers.
  3. Observation: Monitor the time taken for gas bubbles (CO₂) to evolve.
  4. Conclusion: Smaller particles will produce gas more quickly due to a larger surface area, thus increasing the rate of reaction.

Step 3

ii) concentration

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Answer

To demonstrate the effect of concentration on the rate of reaction, follow these steps:

  1. Experimental Setup: Use equal volumes of HCl at different concentrations (e.g., dilute and concentrated).
  2. Procedure: Add equal amounts of marble chips to each beaker containing HCl.
  3. Data Collection: Measure the time taken for the reaction to complete in each setup by observing the volume of gas produced.
  4. Analysis: A higher concentration of acid will result in a faster rate of reaction due to more frequent collisions between reactant particles.

Step 4

What is a catalyst?

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Answer

A catalyst is a substance that alters (speeds up) the rate of a chemical reaction without being consumed in the process. It remains chemically unchanged at the end of the reaction.

Step 5

Identify one reaction which is catalysed in the catalytic converter in a car.

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Answer

One reaction catalyzed in the catalytic converter is the conversion of carbon monoxide (CO) to carbon dioxide (CO₂). This is generally facilitated by a platinum catalyst.

Step 6

State one of the environmental benefits of this process.

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Answer

One environmental benefit of this process is the reduction of toxic emissions, such as carbon monoxide, thus helping to mitigate air pollution and improve air quality.

Step 7

Name one element used as a catalyst in a catalytic converter.

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Answer

One element commonly used as a catalyst in catalytic converters is platinum.

Step 8

What type of catalysis is involved in a catalytic converter?

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Answer

The type of catalysis involved in a catalytic converter is heterogeneous catalysis, where the catalyst is in a different phase (solid) than the reactants (gases).

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