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A stopwatch was started when 50 cm³ of a 0.20 M sodium thiosulfate solution was poured into a conical flask containing 10 cm³ of 1.0 M HCl solution - Leaving Cert Chemistry - Question 3 - 2010

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A stopwatch was started when 50 cm³ of a 0.20 M sodium thiosulfate solution was poured into a conical flask containing 10 cm³ of 1.0 M HCl solution. The conical flas... show full transcript

Worked Solution & Example Answer:A stopwatch was started when 50 cm³ of a 0.20 M sodium thiosulfate solution was poured into a conical flask containing 10 cm³ of 1.0 M HCl solution - Leaving Cert Chemistry - Question 3 - 2010

Step 1

Identify the precipitate produced in each flask.

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Answer

The precipitate produced in each flask is sulfur (S), which forms as a result of the reaction between sodium thiosulfate and hydrochloric acid.

Step 2

Describe a procedure for diluting the 0.20 M sodium thiosulfate solution to give 50 cm³ of a 0.12 M solution.

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Answer

To prepare 50 cm³ of a 0.12 M sodium thiosulfate solution from a 0.20 M stock solution, the following steps should be taken:

  1. Calculate the volume of 0.20 M solution needed using the dilution formula:

    C1V1=C2V2C_1V_1 = C_2V_2

    where C1=0.20C_1 = 0.20 M, C2=0.12C_2 = 0.12 M, and V2=50V_2 = 50 cm³:

    V1=C2V2C1=0.12×500.20=30 cm3V_1 = \frac{C_2V_2}{C_1} = \frac{0.12 \times 50}{0.20} = 30\text{ cm}^3

  2. Measure 30 cm³ of the 0.20 M sodium thiosulfate solution.

  3. Add distilled or deionized water to the 30 cm³ solution to make up the final volume to 50 cm³.

  4. Mix the solution thoroughly.

Step 3

Plot a graph to record the relationship between the concentration of sodium thiosulfate and the rate of reaction.

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To plot the graph, use the provided data to create a scatter plot of the concentration (M) versus the reaction rate (1/t, min⁻¹). Ensure that the x-axis is labeled as 'Concentration (M)' and the y-axis as 'Rate (1/t min⁻¹)'. All points should be plotted accurately, and a straight line should connect them to show the trend.

Step 4

What conclusion can be drawn from the graph about the relationship between the rate and concentration of sodium thiosulfate?

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Answer

The graph demonstrates a direct proportional relationship between the concentration of sodium thiosulfate and the reaction rate, indicating that as the concentration of sodium thiosulfate increases, the rate of reaction also increases.

Step 5

Use your graph to predict the time taken for 50 cm³ of 0.2 M sodium thiosulfate to go cloudy when it is mixed with 10 cm³ of 1.0 M HCl solution at a number of different temperatures.

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Answer

To predict the time for the reaction to occur, one can extrapolate from the graph based on the concentration. For 0.20 M sodium thiosulfate, the time taken was recorded at 1.4 minutes, hence if the temperature increases, one could anticipate a shorter reaction time.

Step 6

Would you expect the time taken to increase, decrease, or stay the same, as the temperature was increased? Justify your answer.

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Answer

The time taken would be expected to decrease as the temperature increases. This is because increasing the temperature generally raises the kinetic energy of the reactant particles, leading to more frequent and effective collisions, thus increasing the reaction rate.

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